The 1,2-addition of α-oxoketene dithioacetals with methallyl Grignard reagent afforded the carbinols 2. 5 and 6 respectively.
缩基
和六
环的α-氧代烯
环二硫代缩
与2-甲基烯丙基氯化镁反应得1,2-加成产物。
The 1,2-addition of α-oxoketene dithioacetals with methallyl Grignard reagent afforded the carbinols 2. 5 and 6 respectively.
缩基
和六
环的α-氧代烯
环二硫代缩
与2-甲基烯丙基氯化镁反应得1,2-加成产物。
hydroxyl ketene dithioacetals possessing an allylalcohol moiety, as well as terminal bisalkylthio substituted alkene are a class of important intermediates in organic synthesis.
羟基二硫缩烯化合物不仅含有烯丙基醇结构单
,而且双键端位被双烷硫基取代,是有机合成中的一
的有机中间体。
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